Researchers seem to have solved the puzzle of LK-99. Scientific detective work has unearthed evidence that the material is not a superconductor, and clarified its actual properties.

The conclusion dashes hopes that LK-99 — a compound of copper, lead, phosphorus and oxygen — marked the discovery of the first superconductor that works at room temperature and ambient pressure. Instead, studies have shown that impurities in the material — in particular, copper sulfide — were responsible for the sharp drops in electrical resistivity and partial levitation over a magnet, which looked similar to properties exhibited by superconductors.

“I think things are pretty decisively settled at this point,” says Inna Vishik, a condensed-matter experimentalist at the University of California, Davis.

The LK-99 saga began in late July, when a team led by Sukbae Lee and Ji-Hoon Kim at the Quantum Energy Research Centre, a start-up firm in Seoul, published preprints1,2 claiming that LK-99 is a superconductor at normal pressure and temperatures up to at least 127 ºC (400 kelvin). All previously confirmed superconductors function only at extreme temperatures and pressures.

The extraordinary claim quickly grabbed the attention of the science-interested public and researchers, some of whom tried to replicate LK-99. Initial attempts did not see signs of room-temperature superconductivity, but were not conclusive. Now, after dozens of replication efforts, many experts are confidently saying that the evidence shows LK-99 is not a room-temperature superconductor. (Lee and Kim’s team did not respond to Nature’s request for comment.) Accumulating evidence

The South Korean team based its claim on two of LK-99’s properties: levitation above a magnet and abrupt drops in resistivity. But separate teams in Beijing, at Peking University3 and the Chinese Academy of Sciences4 (CAS), found mundane explanations for these phenomena.

Another study5, by US and European researchers, combined experimental and theoretical evidence to demonstrate how LK-99’s structure made superconductivity infeasible. And other experimenters synthesized and studied pure samples6 of LK-99, erasing doubts about the material’s structure and confirming that it is not a superconductor, but an insulator.

The only further confirmation would come from the Korean team sharing their samples, says Michael Fuhrer, a physicist at Monash University in Melbourne, Australia. “The burden’s on them to convince everybody else,” he says.

Perhaps the most striking evidence for LK-99’s superconductivity was a video taken by the Korean team that showed a coin-shaped sample of silvery material wobbling over a magnet. The team said the sample was levitating because of the Meissner effect — a hallmark of superconductivity in which a material expels magnetic fields. Multiple unverified videos of LK-99 levitating subsequently circulated on social media, but none of the researchers who initially tried to replicate the findings observed any levitation.

Half-baked levitation

Several red flags popped out to Derrick van Gennep, a former condensed-matter researcher at Harvard University in Cambridge, Massachusetts, who now works in finance but was intrigued by LK-99. In the video, the same edge of the sample seemed to stick to the magnet, and it seemed delicately balanced. By contrast, superconductors that levitate over magnets can be spun and even held upside-down. “None of those behaviors look like what we see in the LK-99 videos,” van Gennep says.

He thought LK-99’s properties were more likely the result of ferromagnetism. So he constructed a pellet of compressed graphite shavings with iron filings glued to it. A video made by Van Gennep shows that his disc — made of non-superconducting, ferromagnetic materials — mimicked LK-99’s behaviour.

On 7 August, the Peking University team reported that this “half-levitation” appeared in their LK-99 samples because of ferromagnetism. “It’s exactly like an iron-filing experiment,” says Yuan Li, a condensed-matter physicist and study co-author. The pellet experiences a lifting force but it’s not enough to levitate — only enough to balance on one end.

Li and his colleagues measured their sample’s resistivity, and found no sign of superconductivity. But they couldn’t explain the sharp resistivity drop seen by the Korean team. Impure samples

In their preprint, the Korean authors note one particular temperature at which LK-99 showed a tenfold drop in resistivity, from about 0.02 ohm-centimetres to 0.002 ohm-cm. “They were very precise about it. 104.8ºC,” says Prashant Jain, a chemist at the University of Illinois Urbana–Champaign. “I was like, wait a minute, I know this temperature.”

The reaction that synthesizes LK-99 uses an unbalanced recipe: for every 1 part it makes of copper-doped lead phosphate crystal — pure LK-99 — it produces 17 parts copper and 5 parts sulfur. These leftovers lead to numerous impurities — especially copper sulfide, which the Korean team reported in its sample.

Jain, a copper-sulfide expert, remembered 104ºC as the temperature at which Cu2S undergoes a phase transition. Below that temperature, the resistivity of air-exposed Cu2S drops dramatically — a signal almost identical to LK-99’s purported superconducting phase transition. “I was almost in disbelief that they missed it.” Jain published a preprint7 on the important confounding effect.

On 8 August, the CAS team reported on the effects of Cu2S impurities in LK-99. “Different contents of Cu2S can be synthesized using different processes,” says Jianlin Luo, a CAS physicist. The researchers tested two samples — the first heated in a vacuum, which resulted in 5% Cu2S content, and the second in air, which gave 70% Cu2S content.

The first sample’s resistivity increased relatively smoothly as it cooled, and appeared similar to samples from other replication attempts. But the second sample’s resistivity plunged near 112 ºC (385K) — closely matching the Korean team’s observations.

“That was the moment where I said, ‘Well, obviously, that’s what made them think this was a superconductor,’” says Fuhrer. “The nail in the coffin was this copper sulfide thing.”

Making conclusive statements about LK-99’s properties is difficult, because the material is finicky and samples contain varying impurities. “Even from our own growth, different batches will be slightly different,” says Li. But Li argues that samples that are close enough to the original are sufficient for checking whether LK-99 is a superconductor in ambient conditions.